Deoxygenating and sterilizing corrosion inhibitor is a multifunctional water treatment agent that integrates deoxygenation, sterilization, and corrosion inhibition functions. It is widely used in the field of industrial water treatment, especially in boiler water treatment, circulating cooling water systems, and other scenarios. The following will introduce it from several aspects, including its definition, principle of action, composition of components, and application scenarios.
Deoxygenating and sterilizing corrosion inhibitors are composite agents developed to address issues such as dissolved oxygen, microbial growth, and corrosion of metal equipment in water systems. It achieves the functions of removing dissolved oxygen in water, killing or inhibiting microbial growth, and slowing down metal corrosion rate through multiple mechanisms of action, thereby ensuring the safe and stable operation of water systems, extending equipment service life, and reducing maintenance costs.
The reaction between ascorbic acid and oxygen is more complex in reality. Through this reaction, dissolved oxygen in water is continuously consumed to maintain its concentration at a lower level.
Various microorganisms, such as bacteria, fungi, and algae, are prone to breed in water systems. These microorganisms can form biofilms on metal surfaces, which not only hinder heat exchange and reduce equipment efficiency, but also accelerate metal corrosion. The bactericidal components in deoxygenating and sterilizing corrosion inhibitors, such as quaternary ammonium compounds, can damage the cell membrane structure of microorganisms, change the permeability of the cell membrane, and cause substances inside the cells to leak out, leading to microbial death. Quaternary ammonium salts carry a positive charge, while microbial cells carry a negative charge. Electrostatic adsorption occurs between them. After entering the cell, quaternary ammonium salts react with proteins or lipids inside the cell, interfering with the normal metabolic process of microorganisms and achieving the purpose of sterilization.
The corrosion inhibitor component in this agent can form a protective film on the metal surface, preventing corrosive media in water (such as water, oxygen, acid, salt, etc.) from directly contacting the metal, thereby slowing down the corrosion rate of the metal. The protective film can be a physical adsorption film, a chemical precipitation film, or an oxide film, etc. For example, some organic amine and organic acid corrosion inhibitors can adsorb onto metal surfaces, changing the charge state and reactivity of the metal surface, making it less prone to react with corrosive media; Phosphate corrosion inhibitors can form insoluble precipitates with calcium, magnesium ions, and other substances in water, depositing a protective film on the metal surface.
Deoxygenating and sterilizing corrosion inhibitors are usually composed of multiple components that work together to exert a comprehensive effect. The common ingredients and their functions are shown in the table below:
|
Component type |
Specific components |
Effect |
|
Oxygen scavengers |
Isoascorbic acid, sodium isoascorbate |
Reacts with dissolved oxygen to reduce oxygen content in water |
|
Fungicide |
Quaternary ammonium salt compounds (such as alkyl trimethylammonium chloride, dimethyl benzyl alkyl ammonium chloride, etc.) |
Destroy microbial cell membranes and kill microorganisms |
|
Corrosion inhibitor |
Organic amines (such as dimethylamine), organic acids (such as oxalic acid, citric acid), phosphates (such as sodium dihydrogen phosphate), sodium epoxysuccinate, sodium hexametaphosphate, polyaspartic acid, etc |
Form a protective film on the metal surface to slow down metal corrosion |
|
Other auxiliary components |
PH regulators, dispersants, etc |
Adjust the pH value of water to enable the medication to function in a suitable acidic and alkaline environment; Disperse suspended solids in water to prevent sedimentation and blockage of pipelines |
During the operation of the boiler, dissolved oxygen in the water can cause oxygen corrosion of the metal heating surface of the boiler, producing corrosion products that affect the thermal efficiency and service life of the boiler. At the same time, the growth of microorganisms in the boiler can form biofouling, block pipelines, and reduce heat transfer efficiency. Deoxygenating and sterilizing corrosion inhibitors can effectively remove dissolved oxygen from water, kill microorganisms, and form a protective film on the metal surface of boilers to prevent corrosion and scaling, ensuring the safe and economical operation of boilers.
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